Mole Concept
Refer to Annex A
Separation Technique
Filtration
Simple Distillation
Crystallisation
Fractional Distillation
Chromatography
Air and Atmosphere
global warming
composition
air pollution and effects
acid rain and effects
Acid, Base and Salts
Acid
React with reactive metals to form salt and H2
React with alkali/ metal oxide to form salt and water
React with carbonate to form salt water and CO2
Non-metal oxide (Acidic oxide) Dissolve in water to form acidic solution
Physical Properties pH 1-6 sour contain H+ ions turn moist blue litmus red
Base
Physical Properties pH 8-14 bitter alkali contains OH- ions turn moist red litmus blue
Metal oxides
Soluble in water
Na,K Alkali React with ammonium salt to give salt, NH3 and Water
Insoluble in water
Amphoteric oxide Zn, Pb, Al
Salts
Soluble
Reaction with Acids Acid + Metal Acid + Base Acid + Carbonate
Are the starting materials for making the salt soluble in water?
Yes
Titration Acid+Alkali Aid+carbonate solution
No
Reaction of acids with insoluble substances Acid + Excess metal (Excluding Na/ K/ Ca/ Cu/ Mg Acid+ Excess insoluble base Aci+excess insoluble carbonate
Qualitative Analysis Refer to Annex B Test for Cation and Anion
Insoluble
Method: Precipitation
Solubility of Salts
Chlorides
All soluble except Ag, Pb
Carbonates
All insoluble except Na,K,NH4
Nitrates
All soluble
Sulphates
All soluble except BaSO4/PbSO4 and CaSO4
Speed of Reaction
Factors Temp of reactants Particle size conc of reactants Pressure (only for gases)
Ammonia
Haber Process N2 +3H2 <--> 2 NH3 (Reversible) finely divided Fe Catalyst 450 degrees celcius 200 atmosphere pressure
Energy Changes
Exo
Energy for bond breaking < Energy for bond forming Temp increase
Endo
Energy for bond breaking > Energy for bond forming Temp decrease
Periodic Table
Metal
Reactivity Series
Popular Scientist Can Make A Zoo In The Lab However Cannot See Girls
Strong Reducing Agent
Stability of Metal Carbonates
Reactions
With acid -> salt +H2
Withwater -> hydroxide/ oxide +H2
Extraction of Metals
By Electrolysis
Active Electrode
Electroplating/Purifying Object to be plated purified metal to be attached to the cathode
Inert Electrode
Molten Compound for extracting reactive metals such as Na/K/Ca/Mg/Al
Dilute aqueous solution
concentrated aqueous solution ions of higher conc will be discharged reactive metal ions can never be discharged
By Reducing agents For extracting low reactivity metals
Non-metal
Group 0 Noble Gases Full electronic configuration
Group VII
Physical Properties Colour states Mp and Bp
Reactivity down the group Displacement reaction (more reactive halogen displaces less reactive ones)
Strong oxidising agent Causes reduction (decrease in oxi# or loss of oxygen or gain in hydrogen)
Transitions
Colour Compound
Variable oxide #
Chemical Bond
Ionic
Formed between metal and non metal by transfer of electrons
giant lattice structure
high mp and bp conducts electricity only in molten and aqueous state
Covalent
formed between non-metals by sharing electrons
giant covalent compounds
strong covalent bonds
Diamond
Tetrahedral structure Does not conduct electricity
Graphite
Hexagonal arrangement of atoms weak vanderwaals force between layers conduct electricity soft and slippery
Simple Covalent Compound
low mp and bp does not conduct electricity
weak intermolecular forces of attraction
Metallic
Interaction between sea of elections and the metallic ions Present in all metals
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